Structure of Electroexplosive Coating of the TiB2-Ni-Ag System
УДК 621.793.79
Abstract
The coating of the TiB2-Ni-Ag system is obtained on a substrate of a copper e1ectrica1 contact by simu1taneous e1ectrica1 exp1osion of si1ver and nicke1 foi1s a1ong with the TiB2 powder 1ocated on the surface of the foi1s. The structure and the transition area between the coating and the copper substrate are investigated using scanning e1ectron microscopy. The coating has an average thickness of 160 ^m and is characterized by a structure with microcrysta11ine and nanocrysta11ine TiB2 inc1usions 1ocated in a si1ver- and nicke1-based matrix. There are periodic wave-1ike structures with micrometer-sized waves at the boundary between the coating and the copper substrate formed as a resu1t of hydrodynamic instabi1ities during the coating process. The nanocrysta11ine structure of the coating at the transition area between the coating and the substrate presents nanosized partic1es of so1id copper, si1ver, and nicke1 so1utions. There are cracks in the copper substrate; they formed by the impact of the shock-compressed 1ayer and extend a1ong the intergranu1ar boundaries.
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References
Braunovic M., Myshkin N.K., Konchits V. V. Electrical Contacts: Fundamentals, Applications and Technology. Boca Raton: CRC Press, 2007. 672 p. https://doi.org/10.1201/9780849391088
Buggy M., Conlon C. Material Selection in the Design of Electrical Con-Nectors. Journal of Materials Processing Technology. 2024. Vol. 153-154. P. 213-218. https://doi.org/10.1016/j.jmatprotec.2004.04.209
Kloch K.T., Kozak P., Mlyniec A. A Review and Perspectives on Predicting the Per-Formance and Durability of Electrical Contacts in Automotive Applications // Engineering Failure Analysis. 2021. Vol. 121. P. 105143. https://doi.org/10.1016/j.engfailanal.2020.105143
Trinh K.E., Tsipenyuk A., Varenberg M., et al. Wear Debris and Electrical Resistance in Textured Sn-Coated Cu Contacts Subjected to Fretting // Wear. 2015. Vol. 344-345. P. 86-98. https://doi.org/10.1016/j.wear.2015.10.010
Cruz-Cruz I., Hernandez-Maya R., Resendiz-Hernandez J.E., et al. Copper-Nickel/SiC Composites for Applications on Contact Electrodes // Heliyon. 2024. Vol. 10. P. e39965. https:// doi.org/10.1016/j.heliyon.2024.e39965
Song J., Yuan H., Schinow V. Fretting Corrosion Behavior of Electrical Contacts With Tin Coating in Atmosphere and Vacuum // Wear. 2019. Vol. 426-427. P. 1439-1445. https:// doi.org/10.1016/j.wear.2018.11.024
Kumar S.P., Parameshwaran R., Kumar S.A., et al. Electrical and Mechanical Studies on Pure-Silver Coated Aluminium Based Electrical Contact Materials // Heenalisha. 2020. Vol. 33. P. 3621-3625. https://doi.org/10.1016/j.matpr.2020.05.666
Suryanarayana C. Mechanical Alloying: a Critical Review // Materials Research Letters. 2022. Vol. 10. P. 619-647. https://doi.org/10.1080/21663831.2022.2075243
Ramanathan A. A Review on the Production of Metal Matrix Composites Through Stir Casting-Furnace Design, Properties, Challenges, and Research Oppor-Tunities // Journal of Manufacturing Processes. 2019. Vol. 42. P. 213-245. https://doi.org/10.1016/j.jmapro.2019.04.017
Suryanarayana C. Mechanical Alloying and Milling // Progress in Materials Science. 2001. Vol. 46. P. 1-184. https://doi.org/10.1016/S0079-6425(99)00010-9
Suryanarayana C. Mechanical Alloying: a Critical Review // Materials Research Letters. 2022. Vol. 10. P. 619-647. https://doi.org/10.1080/21663831.2022.2075243
Mukhopadhyay A., Basu B. Consolidation-Micro-structure-Property Relation-Ships in Bulk Nanoceramics and Ceramic Nanocomposites: a Review // International Materials Reviews. 2007. Vol. 52. P. 257-288. https://doi.org/10.1179/174328007X160281
Eessaa A.K., Elkady O.A., El-Shamy A.M. Powder Metallurgy as a Perfect Technique for Preparation of Cu-TiO2 Composite by Identifying Their Micro structure and Optical Properties // Scientific Reports. 2023. Vol. 13. P. 7034. https://doi.org/10.1038/s41598-023-33999-y
Zhu L., Xue P., Lan Q., et al. Recent Research and Development Status of Laser Cladding: A Review // Optics & Laser Technology. 2021. Vol. 138. P. 106915. https://doi.org/10.1016/j.optlastec.2021.106915
Davis J.R. Handbook of Thermal Spray Technology. Ohio: ASM International, 2004. 344 p.
Vuoristo P. Thermal Spray Coating Processes. Amsterdam: Elsevier, 2014. P. 229-276.
Bataev I.A., Riabinkina P.A., Emurlaev K.I., et al. Uncovering the Influence of Mechanical Properties on Wave Formation During High-Velocity Impact Welding by Numerical Simulation // Journal of Materials Processing Technology. 2024. Vol. 332. P. 18532. https://doi.org/10.1016/j.jmatprotec.2024.118532
Shtertser A.A., Batraev I.S., Ulianitsky V.Yu., et al. Detonation Spraying of Ti-Cu Mixtures in Different Atmospheres: Carbon, Nitrogen and Oxygen Uptake by the Powders // Surfaces and Interfaces. 2020. Vol. 21. P. 100676. https://doi.org/10.1016/j.surfin.2020.100676
Raoelison R.N., Xie Y., Sapanathan T., et al. Cold Gas Dynamic Spray Technology: A Compre-Hensive Review of Processing Conditions for Various Technological Developments Till to Date // Additive Manufacturing. 2018. Vol. 19. P. 134159. https://doi.org/10.1016/j.addma.2017.07.001
Filyakov A.D., Pochetukha V.V., Romanov D.A., et al. Influence of Electron Beam Treatment on Structure and Phase Composition of TiB2-Ag Coating Deposited by Electrical Explosion Spraying // Coatings. 2023. Vol. 13 (11). P. 1867. https://doi.org/10.3390/coatings13111867
Copyright (c) 2026 Василий Витальевич Почетуха, Денис Анатольевич Романов, Екатерина Степанова Ващук, Виктор Евгеньевич Громов

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