Potentiodynamic Study of the Anodic Behavior of Zn5Al Alloy Doped with Manganese

УДК 66.046.516:546.711

  • F.A. Rakhimov V.I. Nikitin Institute of Chemistry AS (Dushanbe, Tajikistan) Email: r.f.a-040891@bk.ru
  • Z.R. Obidov V.I. Nikitin Institute of Chemistry AS (Dushanbe, Tajikistan) Email: z.r.obidov@rambler.ru
  • R.N. Amini Golpaigansk University of Technology (Isfahan, Iran) Email: reza.amini@mail.ru
  • I.N. Ganiev V.I. Nikitin Institute of Chemistry AS (Dushanbe, Tajikistan) Email: ganiev48@mail.ru
  • V.A. Novozhenov Altai State University (Barnaul, Russia) Email: novozenov@mail.asu.ru
  • N.E. Strucheva Altai State University (Barnaul, Russia) Email: strucheva@chem.asu.ru
DOI_disc_logo https://doi.org/10.14258/izvasu(2020)4-08
Keywords: zinc, aluminum, alloys, alloying, phase

Abstract

The widespread use of zinc-aluminum alloys as protective coatings for structures, products, and structures requires studying the effect of various additives in such alloys on their corrosion resistance in various environments. In studying the anode behavior of alloys, potentiodynamic methods are widely used to select methods of protection and increase the stability of anode alloys under given operating conditions. The article presents the results of a potentiodynamic study of the corrosion-electrochemical behavior of Zn5Al alloys doped with manganese in various electrolytes. An increase in the manganese concentration within the studied concentrations leads to a shift in the standard potential and pitting potential to a positive region compared to the initial Zn5Al alloy, which indicates a decrease in the corrosion rate of the studied alloys by 2-2.5 times with respect to the base alloy. An increase in the concentration of chloride ions in the electrolyte leads to a decrease in the electrochemical potentials of corrosion and pitting formation of alloys, which indicates an increase in their anode stability. An increase in the anode stability of the protective coatings of alloys depends on the time spent in an aggressive environment: the longer the time, the lower the rate of anode dissolution.

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Author Biographies

F.A. Rakhimov, V.I. Nikitin Institute of Chemistry AS (Dushanbe, Tajikistan)

научный сотрудник лаборатории коррозионностойких материалов

Z.R. Obidov, V.I. Nikitin Institute of Chemistry AS (Dushanbe, Tajikistan)

доктор химических наук, доцент

R.N. Amini, Golpaigansk University of Technology (Isfahan, Iran)

кандидат технических наук, научный сотрудник

I.N. Ganiev, V.I. Nikitin Institute of Chemistry AS (Dushanbe, Tajikistan)

доктор химических наук, профессор

V.A. Novozhenov, Altai State University (Barnaul, Russia)

доктор химических наук, профессор, профессор кафедры физической и неорганической химии

N.E. Strucheva, Altai State University (Barnaul, Russia)

кандидат химических наук, доцент, доцент кафедры физической и неорганической химии

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Published
2020-09-09
How to Cite
Rakhimov F., Obidov Z., Amini R., Ganiev I., Novozhenov V., Strucheva N. Potentiodynamic Study of the Anodic Behavior of Zn5Al Alloy Doped with Manganese // Izvestiya of Altai State University, 2020, № 4(114). P. 53-58 DOI: 10.14258/izvasu(2020)4-08. URL: http://izvestiya.asu.ru/article/view/%282020%294-08.
Issue
No 4(114) (2020): Izvestiya of Altai State University
Section
Физика

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